Thermodynamic and kinetic analysis of methylene blue adsorption onto chemically modified cotton
DOI:
https://doi.org/10.18265/2447-9187a2025id8887Palavras-chave:
adsorption, cotton, carboxylation, methylene blue, thermodynamicsResumo
This study investigates the adsorption of methylene blue onto chemically modified cotton, focusing on the kinetic and thermodynamic aspects of the process. The primary objective is to assess how chemical modification through carboxylation enhances the interaction between the methylene blue dye and the adsorbent material. The research is grounded in adsorption and thermodynamic theories, addressing the interactions between the dye and the modified substrate. The methodology includes the carboxylation of cotton using monochloroacetic acid and the execution of adsorption experiments at varying dye concentrations, ranging from 1 to 100 mg·L-1, along with kinetic and thermodynamic evaluations. The results demonstrate that cotton carboxylation significantly increases the adsorption capacity for methylene blue, with kinetic data fitting well to the pseudo-second-order model. Thermodynamic analysis indicates that the adsorption process is spontaneous and favorable, characterized by an increase in enthalpy, suggesting that the interactions between the dye and the modified substrate are chemical in nature. Furthermore, adsorption is enhanced at higher temperatures, indicating that temperature positively influences the efficiency of the process. The maximum adsorption capacities obtained were comparable to or exceeded those reported for other low-cost natural adsorbents, highlighting the potential of chemically modified cotton as an effective material for dye removal from effluents. Integrating chemical modification strategies with adsorption dynamics presents promising opportunities for developing innovative purification technologies.
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